Imaging beta-galactosidase activity using 19F chemical shift imaging of LacZ gene-reporter molecule 2-fluoro-4-nitrophenol-beta-D-galactopyranoside

Magn Reson Imaging. 2006 Sep;24(7):959-62. doi: 10.1016/j.mri.2006.04.003. Epub 2006 Jun 8.

Abstract

2-Fluoro-4-nitrophenol-beta-D-galactopyranoside (OFPNPG) belongs to a novel class of NMR active molecules (fluoroaryl-beta-D-galactopyranosides), which are highly responsive to the action of beta-galactosidase (beta-gal). OFPNPG has a single 19F peak (-55 ppm relative to aqueous sodium trifluoroacetate). Upon cleavage by beta-gal, the pH sensitive aglycone 2-fluoro-4-nitrophenol (OFPNP) is observed at a chemical shift of -59 to -61 ppm. The chemical shift response is sufficient to observe beta-gal activity using chemical shift imaging (CSI). 19F CSI studies of enzyme activity and lacZ gene expression in 9L-glioma and MCF7 breast cancer cells are presented, providing further evidence for the utility of OFPNPG as a gene-reporter molecule for future in vivo studies.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Breast Neoplasms / genetics
  • Breast Neoplasms / metabolism
  • Escherichia coli / enzymology
  • Fluorine Radioisotopes
  • Genes, Reporter / genetics*
  • Glioma / genetics
  • Glioma / metabolism
  • Humans
  • Lac Operon / genetics*
  • Magnetic Resonance Spectroscopy / methods*
  • Nitrophenylgalactosides*
  • Promoter Regions, Genetic / genetics
  • Radiopharmaceuticals
  • Transfection
  • beta-Galactosidase / genetics
  • beta-Galactosidase / metabolism*

Substances

  • 2-fluoro-4-nitrophenyl galactopyranoside
  • Fluorine Radioisotopes
  • Radiopharmaceuticals
  • Nitrophenylgalactosides
  • beta-Galactosidase