Steric control of a bridging ligand for high-nuclearity metallamacrocycle formation: a highly puckered 60-membered icosanuclear metalladiazamacrocycle

Dohyun Moon; Kyungjae Lee; Rohith P John; Ghyung Hwa Kim; Byoung Jin Suh; Myoung Soo Lah

doi:10.1021/ic060646d

Steric control of a bridging ligand for high-nuclearity metallamacrocycle formation: a highly puckered 60-membered icosanuclear metalladiazamacrocycle

Inorg Chem. 2006 Oct 2;45(20):7991-3. doi: 10.1021/ic060646d.

Authors

Dohyun Moon¹, Kyungjae Lee, Rohith P John, Ghyung Hwa Kim, Byoung Jin Suh, Myoung Soo Lah

Affiliation

¹ Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do 426-791, Korea.

PMID: 16999391
DOI: 10.1021/ic060646d

Abstract

A novel S4-symmetric icosanuclear manganese metalladiazamacrocycle was synthesized using a pentadentate ligand, N-3-phenyl-trans-2-propenoylsalicylhydrazide (H3L), that has a rigid and bulky terminal N-acyl group. A 20 cyclic repeat of an--(Mn-N-N)--linkage resulted in a highly puckered diaza-bridged 60-membered icosanuclear metallamacrocycle. The steric interaction between the ligands in the cyclic system leads to five consecutive Mn(III) centers in a chemically different--(Mn(A)Mn(B)Mn(C)Mn(D)Mn(E))--environment, with the chiralities of the metal centers being in a rather complicated--(LambdaLambdaDeltaLambdaLambda)(DeltaDeltaLambdaDeltaDelta)--sequence.