Tetrametallic rectangular box complexes assembled from heteroligated macrocycles

Chem Commun (Camb). 2006 Nov 13:(42):4386-8. doi: 10.1039/b609931a. Epub 2006 Oct 3.

Abstract

The reaction of a heteroligated Rh(I) bimetallic macrocycle with rigid ditopic ligands (1,4-dicyanobenzene, 4-4'-dicyanobiphenyl, or dipyridyl terminated salen ligand 5) results in the formation of tetrametallic rectangular box complexes.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Copper / chemistry
  • Ligands
  • Macrocyclic Compounds / chemical synthesis
  • Macrocyclic Compounds / chemistry*
  • Models, Chemical
  • Models, Molecular
  • Molecular Structure
  • Platinum / chemistry
  • Rhenium / chemistry*
  • Silver / chemistry

Substances

  • Ligands
  • Macrocyclic Compounds
  • Silver
  • Platinum
  • Rhenium
  • Copper