Stereoelectronic effects dictate mechanistic dichotomy between Cu(II)-catalyzed and enzyme-catalyzed reactions of malonic acid half thioesters

J Am Chem Soc. 2007 Feb 7;129(5):1032-3. doi: 10.1021/ja0673682.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Aldehydes / chemistry
  • Catalysis
  • Cations, Divalent
  • Copper / chemistry*
  • Enzyme Activation
  • Esters / chemistry*
  • Kinetics
  • Malonates / chemistry*
  • Models, Chemical
  • Sulfhydryl Compounds / chemistry*

Substances

  • Aldehydes
  • Cations, Divalent
  • Esters
  • Malonates
  • Sulfhydryl Compounds
  • Copper
  • malonic acid