Abstract
A detailed account on the stereoselective total syntheses of azaphenalene alkaloids via an intramolecular aza-[3+3] annulation strategy is described here. All five members of the Coccinellidae family of defensive alkaloids were prepared from the same common intermediate, which was derived from a stereoselective aza-[3+3] annulation reaction.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Alkaloids / chemistry*
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Aza Compounds / chemistry*
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Carmine / analogs & derivatives*
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Carmine / chemical synthesis
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Carmine / chemistry
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Lactams / chemistry
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Models, Molecular
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Molecular Structure
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Oxidation-Reduction
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Propanols / chemistry
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Quinazolines / chemistry
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Water / chemistry
Substances
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Alkaloids
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Aza Compounds
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Lactams
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Propanols
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Quinazolines
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hippodamine
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myrrhine
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Water
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allyl alcohol
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Carmine