195Pt NMR--theory and application

Chem Soc Rev. 2007 Apr;36(4):665-86. doi: 10.1039/b606190g. Epub 2006 Nov 17.

Abstract

This critical review highlights the progress in (195)Pt NMR over the last 25 years. In particular, some of the recent applications of (195)Pt NMR in catalytic and mechanistic studies, intermetallics and drug binding studies are discussed. (195)Pt NMR chemical shifts obtained from both theoretical studies and experiments are presented for Pt(0), Pt(II), Pt(III) and Pt(IV) complexes. (195)Pt coupling with various nuclei (viz. coupling constants) have also been collected in addition to data on (195)Pt relaxation. The latest developments in the theoretical knowledge and experimental advances have made (195)Pt NMR into a rich source of information in many fields. (164 references.).

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Catalysis
  • Isotopes / chemistry
  • Magnetic Resonance Spectroscopy / methods*
  • Magnetic Resonance Spectroscopy / standards
  • Molecular Structure
  • Organoplatinum Compounds / chemistry*
  • Platinum / chemistry*
  • Platinum Compounds / chemistry*
  • Stereoisomerism

Substances

  • Isotopes
  • Organoplatinum Compounds
  • Platinum Compounds
  • Platinum