Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies

Saad K Ibrahim; Xiaoming Liu; Cédric Tard; Christopher J Pickett

doi:10.1039/b617399c

Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies

Chem Commun (Camb). 2007 Apr 21:(15):1535-7. doi: 10.1039/b617399c. Epub 2007 Jan 30.

Authors

Saad K Ibrahim¹, Xiaoming Liu, Cédric Tard, Christopher J Pickett

Affiliation

¹ School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK.

PMID: 17406699
DOI: 10.1039/b617399c

Abstract

We report the assembly of the first electropolymeric materials incorporating catalytic diiron subsites related to those of the iron-only hydrogenases.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Cyanides / chemistry
Electrochemistry / methods*
Esters / chemistry
Hydrogenase / chemical synthesis
Hydrogenase / chemistry*
Iron Compounds / chemistry
Organometallic Compounds / chemical synthesis
Organometallic Compounds / chemistry*
Polymers / chemical synthesis
Polymers / chemistry*
Pyrroles / chemical synthesis
Pyrroles / chemistry*
Sulfur / chemistry

Substances

Cyanides
Esters
Iron Compounds
Organometallic Compounds
Polymers
Pyrroles
Sulfur
Hydrogenase