trans-Diaqua{5,5'-[(E,E)-pyridine-2,6-diylbis(methylidynenitrilo)]bis[pyrimidine-2,4(1H,3H)-dione]}zinc(II) nitrate hexafluorophosphate trihydrate

Acta Crystallogr C. 2007 Apr;63(Pt 4):m147-9. doi: 10.1107/S0108270107008633. Epub 2007 Mar 17.

Abstract

The title compound, [Zn(C(15)H(11)N(7)O(4))(H(2)O)(2)](NO(3))(PF(6)).3H(2)O, contains a mononuclear zinc(II) complex. The Zn(2+) centre is seven-coordinated in a slightly distorted pentagonal-bipyramidal geometry, with the two water O atoms located in the apical positions, and the pyridine N atom, the two imine N atoms and two carbonyl O atoms of the uracil groups located in the equatorial plane. The charge is balanced by PF(6)(-) and NO(3)(-) anions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrocarbons, Fluorinated / chemistry*
  • Molecular Structure
  • Nitrates / chemistry*
  • Organometallic Compounds / chemistry*
  • Pyrimidines / chemistry*
  • Uracil / analogs & derivatives*
  • Uracil / chemistry
  • Zinc / chemistry*

Substances

  • Hydrocarbons, Fluorinated
  • Nitrates
  • Organometallic Compounds
  • Pyrimidines
  • diaqua(5,5'-(pyridine-2,6-diylbis(methylidynenitrilo))bis(pyrimidine-2,4(1H,3H)-dione))zinc(II)
  • Uracil
  • Zinc
  • pyrimidine