Aldolase provides an unusual binding site for thrombospondin-related anonymous protein in the invasion machinery of the malaria parasite

Proc Natl Acad Sci U S A. 2007 Apr 24;104(17):7015-20. doi: 10.1073/pnas.0605301104. Epub 2007 Apr 10.

Abstract

An actomyosin motor located underneath the plasma membrane drives motility and host-cell invasion of apicomplexan parasites such as Plasmodium falciparum and Plasmodium vivax, the causative agents of malaria. Aldolase connects the motor actin filaments to transmembrane adhesive proteins of the thrombospondin-related anonymous protein (TRAP) family and transduces the motor force across the parasite surface. The TRAP-aldolase interaction is a distinctive and critical trait of host hepatocyte invasion by Plasmodium sporozoites, with a likely similar interaction crucial for erythrocyte invasion by merozoites. Here, we describe 2.4-A and 2.7-A structures of P. falciparum aldolase (PfAldo) obtained from crystals grown in the presence of the C-terminal hexapeptide of TRAP from Plasmodium berghei. The indole ring of the critical penultimate Trp-residue of TRAP fits snugly into a newly formed hydrophobic pocket, which is exclusively delimited by hydrophilic residues: two arginines, one glutamate, and one glutamine. Comparison with the unliganded PfAldo structure shows that the two arginines adopt new side-chain rotamers, whereas a 25-residue subdomain, forming a helix-loop-helix unit, shifts upon binding the TRAP-tail. The structural data are in agreement with decreased TRAP binding after mutagenesis of PfAldo residues in and near the induced TRAP-binding pocket. Remarkably, the TRAP- and actin-binding sites of PfAldo seem to overlap, suggesting that both the plasticity of the aldolase active-site region and the multimeric nature of the enzyme are crucial for its intriguing nonenzymatic function in the invasion machinery of the malaria parasite.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Amino Acid Sequence
  • Amino Acid Substitution
  • Animals
  • Binding Sites
  • Fructose-Bisphosphate Aldolase / chemistry*
  • Fructose-Bisphosphate Aldolase / metabolism*
  • Indoles / chemistry
  • Malaria, Falciparum / parasitology*
  • Molecular Sequence Data
  • Mutation / genetics
  • Plasmodium falciparum / enzymology*
  • Plasmodium falciparum / pathogenicity*
  • Protein Binding
  • Protein Structure, Secondary
  • Protozoan Proteins / chemistry
  • Protozoan Proteins / metabolism*
  • Substrate Specificity

Substances

  • Indoles
  • Protozoan Proteins
  • thrombospondin-related adhesive protein, protozoan
  • indole
  • Fructose-Bisphosphate Aldolase

Associated data

  • PDB/2EPH
  • PDB/2PC4