Differential mode excitation photoacoustic spectroscopy: a new photoacoustic detection scheme

Rev Sci Instrum. 2007 Jun;78(6):063104. doi: 10.1063/1.2746817.

Abstract

A robust and simple gas sensor based on a novel photoacoustic scheme named "differential mode excitation photoacoustic spectroscopy (DME-PAS)" is presented. This method takes advantage of the selective excitation of two different modes in a resonant photoacoustic cell. A blackbody light source is used for simplicity in combination with optical correlation to provide a good selectivity. The frequency response of the proposed resonant cell is modeled using the extended Helmholtz resonator theory. The DME-PAS device is tested using acetone vapor and a model developed to describe its response when the gas concentration is varied. The obtained limit of detection is 25 ppm m(-1) for acetone in room air. Using DME-PAS, the derived gas concentration is affected neither by intensity fluctuations of the light source nor by any microphone drifts.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acoustics / instrumentation*
  • Equipment Design
  • Equipment Failure Analysis
  • Gases / analysis*
  • Photometry / instrumentation*
  • Photometry / methods
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Spectrum Analysis / instrumentation*
  • Spectrum Analysis / methods

Substances

  • Gases