Mechanistic study of competitive sp(3)-sp(3) and sp(2)-sp(3) carbon-carbon reductive elimination from a platinum (IV) center and the isolation of a C-C agostic complex

J Am Chem Soc. 2007 Aug 8;129(31):9538-9. doi: 10.1021/ja066195d. Epub 2007 Jul 13.

Authors

Brian L Madison¹, Summer B Thyme, Sarra Keene, B Scott Williams

Affiliation

¹ The Joint Science Department of The Claremont Colleges, Scripps, Pitzer, and Claremont McKenna College, W. M. Keck Science Center, 925 North Mills Avenue, Claremont, California 91711, USA.

PMID: 17629265
DOI: 10.1021/ja066195d

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbon / chemistry*
Molecular Structure
Oxidation-Reduction
Platinum / chemistry*

Substances

Platinum
Carbon