Complete (1)H and (13)C NMR spectral assignment of alpha- and beta-adenosine, 2'-deoxyadenosine and their acetate derivatives

Magn Reson Chem. 2007 Sep;45(9):781-4. doi: 10.1002/mrc.2036.

Abstract

(1)H and (13)C NMR chemical shifts of alpha- and beta-anomers of adenosine, 2'-deoxyadenosine and their acetate derivatives were completely and definitely assigned using the concerted application of one- and two-dimensional experiments (gCOSY, gNOESY, gHSQC and gHMBC). The influence of the stereochemistry of the purine base on the NMR data of the hydrogen and carbon atoms of the furanose moiety was estimated.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetates / chemistry
  • Adenosine / analogs & derivatives*
  • Adenosine / chemistry*
  • Deoxyadenosines / chemistry*
  • Indicators and Reagents
  • Magnetic Resonance Spectroscopy
  • Mass Spectrometry
  • Stereoisomerism

Substances

  • Acetates
  • Deoxyadenosines
  • Indicators and Reagents
  • Adenosine
  • 2'-deoxyadenosine