Direct Measurement of the Angular Dependence of Ionization for N2, O2, and CO2 in Intense Laser Fields

Phys Rev Lett. 2007 Jun 15;98(24):243001. doi: 10.1103/PhysRevLett.98.243001. Epub 2007 Jun 11.


We experimentally measure the ionization probability as a function of alignment angle of three molecules in intense laser fields: nitrogen, oxygen, and carbon dioxide. Unlike atoms, molecules have a rotational degree of freedom. By controlling the alignment of the molecule relative to the laser field, molecules offer additional ways to understand strong-field ionization. The angular dependence of ionization directly maps to the orbital symmetry of each molecule. Carbon dioxide is seen to have a very sharp preference for ionization when aligned at 45 degrees to the laser field, in significant disagreement with current theories.