Synthesis of salicylaldehyde-modified mesoporous silica and its application as a new sorbent for separation, preconcentration and determination of uranium by inductively coupled plasma atomic emission spectrometry

Mohammad Reza Jamali; Yaghoub Assadi; Farzaneh Shemirani; Mohammad Reza Milani Hosseini; Reyhaneh Rahnama Kozani; Majid Masteri-Farahani; Masoud Salavati-Niasari

doi:10.1016/j.aca.2006.07.006

Synthesis of salicylaldehyde-modified mesoporous silica and its application as a new sorbent for separation, preconcentration and determination of uranium by inductively coupled plasma atomic emission spectrometry

Anal Chim Acta. 2006 Oct 2;579(1):68-73. doi: 10.1016/j.aca.2006.07.006. Epub 2006 Jul 8.

Authors

Mohammad Reza Jamali¹, Yaghoub Assadi, Farzaneh Shemirani, Mohammad Reza Milani Hosseini, Reyhaneh Rahnama Kozani, Majid Masteri-Farahani, Masoud Salavati-Niasari

Affiliation

¹ School of Chemistry, University College of Science, University of Tehran, Tehran, Iran.

PMID: 17723729
DOI: 10.1016/j.aca.2006.07.006

Abstract

A new functionalized mesoporous silica (MCM-41) using salicylaldehyde was utilized for the separation, preconcentration and determination of uranium in natural water by inductively coupled plasma atomic emission spectrometry (ICP-AES). Experimental conditions for effective adsorption of trace levels of U(VI) were optimized. The preconcentration factor was 100 (1.0 mL of elution for a 100 mL sample volume). The analytical curve was linear in the range 2-1000 microg L(-1) and the detection limit was 0.5 ng mL(-1). The relative standard deviation (R.S.D.) under optimum conditions was 2.5% (n=10). Common coexisting ions did not interfere with the separation and determination of uranium at pH 5. The sorbent exhibited excellent stability and its sorption capacity under optimum conditions has been found to be 10mg of uranium per gram of sorbent. The method was applied for the recovery and determination of uranium in different water samples.