Normal atmosphere: large radical and formaldehyde concentrations predicted

Science. 1971 Jul 9;173(3992):141-3. doi: 10.1126/science.173.3992.141.

Abstract

A steady-state model of the normal (unpolluted) surface atmosphere predicts a daytime concentration of hydroxyl, hydroperoxyl, and methylperoxyl radicals approaching 5 x 10(8)molecules per cubic centimeter and a formaldehyde concentration of 5 x 10(10) molecules per cubic centimeter or 2 parts per billion. A radical chain reaction is proposed for the rapid removal of carbon monoxide, leading to a carbon monoxide lifetime as low as 0.2 year in the surface atmosphere.