Tetrakis(mu-benzoato-kappa2O:O)bis{[4-(dimethylamino)pyridine-kappaN1]copper(II)}

Acta Crystallogr C. 2007 Sep;63(Pt 9):m392-4. doi: 10.1107/S0108270107034944. Epub 2007 Aug 9.

Abstract

The title compound, [Cu2(C(7)H(5)O(2))4(C(7)H(10)N(2))2], is a crystallographically centrosymmetric binuclear complex, with Cu atoms [Cu...Cu = 2.6982 (4) A] bridged by four benzoate ligands. Each of the Cu atoms in this bunuclear copper(II) acetate hydrate analogue is present in an approximately square-pyramidal environment, with four O atoms in a plane and the pyridine N atom at the apical site. Selected geometric parameters are compared with values for related tetrabenzoate complexes of copper(II).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzoates / chemistry*
  • Copper / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Organometallic Compounds / chemistry*
  • Pyridines / chemistry*

Substances

  • Benzoates
  • Organometallic Compounds
  • Pyridines
  • tetrakis(mu-benzoato-kappa(2)O:O)bis((4-(dimethylamino)pyridine-kappaN(1))copper(II))
  • Copper