Skip to main page content
Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
, 251 (4995), 786-8

Baddeleyite-Type High-Pressure Phase of TiO2

Baddeleyite-Type High-Pressure Phase of TiO2

H Sato et al. Science.

Abstract

A high-pressure phase of TiO(2), which had been observed by shock-wave experiments and remained unresolved, has been studied by in situ x-ray diffraction. The single phase was formed at 20 gigapascals and 770 degrees C with the use of sintered-diamond multianvils; it has the same structure as baddeleyite, the stable phase of ZrO(2) at ambient conditions. The coordination number of Ti increases from six to seven across the rutile to baddeleyite transition, and the volume is reduced by approximately 9 percent.

Similar articles

See all similar articles

Cited by 4 articles

LinkOut - more resources

Feedback