Photocatalytic TiO2 coatings on bio-degradable plastic(polybutylene succinate: PBS) were prepared by HVOF spraying using three kinds of agglomerated powders (P200: 200 nm, P30: 30 nm, P7: 7 nm). The microstructures of the coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of the coatings was evaluated by photo degradation of gaseous acetaldehyde. For both the HVOF sprayed P200 and P30 coatings, high anatase ratio of 100% was achieved, regardless of the fuel gas pressure. On the other hand, for the HVOF sprayed P7 coating, the anatase ratio decreased from 100% to 49.1% with increasing fuel gas pressure. This decrease may be attributed to the much higher susceptibility to heat of the 7 nm agglomerated powders than the 30 nm and 200 nm agglomerated powders. In terms of the photocatalytic efficiency, HVOF sprayed P200 and P30 coatings seemed to outperform the P7 coatings because of their higher anatase ratios. However, the HVOF sprayed P7 coatings did not show photocatalytic activity possibly because of the extremely small reaction surface area to the photo-catalytic activity and low anatase ratio. Therefore, the present study found that functional PBS plastic with photocatalytic performance could be produced by spraying of ceramics such as TiO2.