Utilization of steel-making slag for the uptake of ammonium and phosphate ions from aqueous solution

J Hazard Mater. 2008 Aug 15;156(1-3):156-62. doi: 10.1016/j.jhazmat.2007.12.009. Epub 2007 Dec 14.

Abstract

Steel-making slag, a waste by-product of the Steel Industry, constitutes a major disposal problem. In the present study, excellent adsorbent materials for reducing eutrophication in wastewaters have been prepared from this slag. Heated samples of acid-treated slag and mixtures of slag with kaolinite and Al(OH)(3) were examined to determine their uptake capacities for NH(4)(+) and PO(4)(3-) from aqueous solutions. In general, the equilibrium pH of the solution increased in comparison to initial pH with the uptake of target ions, the sample activated slag-Al(OH)(3) showing the smallest change. The highest PO(4)(3-) uptake capacity was obtained with the slag-Al(OH)(3) mixture heated at 900 degrees C whereas the highest uptake of NH(4)(+) was found in the slag-Al(OH)(3) mixture heated at 800 degrees C. The uptake rates for PO(4)(3-) and NH(4)(+) by the slag-Al(OH)(3) mixture heated at 900 degrees C were 2.91 and 0.65 micro mol/(g min), respectively. It was shown that heating slag composites prior to incorporation into wastewater treatment filters resulted in an increased degree of NH(4)(+) and PO(4)(3-) uptake.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Kinetics
  • Phosphates / chemistry*
  • Quaternary Ammonium Compounds / chemistry*
  • Solutions
  • Steel*
  • Water
  • X-Ray Diffraction

Substances

  • Phosphates
  • Quaternary Ammonium Compounds
  • Solutions
  • Water
  • Steel