"Schizoid" reactivity of 1,1'-diisocyanoferrocene

Chem Commun (Camb). 2007 Nov 7:(41):4227-9. doi: 10.1039/b709063c.

Abstract

The two chemically equivalent functional groups of 1,1'-diisocyanoferrocene each undergo a different specific reaction with the gold(I) acetylide [Au(C=C-Fc)], viz. ordinary coordination and extraordinary 1,1-insertion.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkynes / chemistry*
  • Ferrous Compounds / chemistry*
  • Gold / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry

Substances

  • 1,1'-diisocyanoferrocene
  • Alkynes
  • Ferrous Compounds
  • Organometallic Compounds
  • Gold