Implementation of an iterative algorithm for optimal control of molecular dynamics into MCTDH

Phys Chem Chem Phys. 2008 Feb 14;10(6):850-6. doi: 10.1039/b714821f. Epub 2007 Dec 10.

Abstract

We have extended a previously implemented algorithm for using optimal control theory within the multi-configurational time-dependent Hartree (MCTDH) software. The new implementation allows the use of arbitrary dipole operators for generating the optimal laser field. A variant that does not require saving the time-dependent wave function has been developed, where simultaneous forward and backward propagations are performed. Input parameters are concentrated in a single input file analogous to the input files used elsewhere in MCTDH. We use here two simple examples to demonstrate the use of OCT-MCTDH: the modified Henon-Heiles potential and a two-dimensional model of acetylene. For both systems, a controlled transition between two vibrational states is tested. Results obtained with MCTDH and exact calculations are compared.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetylene / chemistry
  • Algorithms*
  • Computer Simulation*
  • Lasers
  • Models, Chemical*
  • Quantum Theory*
  • Software
  • Time Factors
  • Vibration

Substances

  • Acetylene