Enhanced cooperative quantum cutting in Tm3+- Yb3+ codoped glass ceramics containing LaF3 nanocrystals

Opt Express. 2008 Jun 9;16(12):8989-94. doi: 10.1364/oe.16.008989.

Abstract

Tm(3+)-Yb(3+) codoped transparent oxyfluoride glass ceramics containing LaF(3) nanocrystals were obtained by thermal treatment on the as-made glasses. The formation of LaF(3) nanocrystals and the incorporation of Tm(3+) and Yb(3+) into LaF(3) nanocrystal lattice were confirmed by X-ray diffraction and high resolution transmission electron microscopy. Infrared quantum cutting involving Yb(3+) 950-1100 nm ((2)F(5/2)--> (2)F(7/2)) emission was achieved upon the excitation of the (1)G(4) energy level of Tm(3+) at 468 nm. We measured the photoluminescence properties of these glass ceramics. We also investigated the thermal treatment duration dependent quantum efficiency, and found that the quantum efficiency is 13% increased for the 0.5Tm(3+)-4Yb(3+) doped glass ceramic with a maximum value of 144%, and 16% increased for the 0.5Tm3+-8Yb3+ doped glass ceramic with a maximum value of 162%, respectively.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ceramics / chemistry*
  • Computer Simulation
  • Equipment Design
  • Equipment Failure Analysis
  • Fluorides / chemistry*
  • Glass / chemistry*
  • Lanthanum / chemistry*
  • Light
  • Materials Testing
  • Models, Theoretical*
  • Quantum Dots*
  • Quantum Theory
  • Refractometry
  • Scattering, Radiation

Substances

  • lanthanum trifluoride
  • Lanthanum
  • Fluorides