Radical cyclization of vinylic ethers: expedient synthesis of (+)-monocerin

Org Lett. 2008 Jul 17;10(14):2995-6. doi: 10.1021/ol801020w. Epub 2008 Jun 13.

Abstract

Stereoselective synthesis of (+)-monocerin was accomplished via radical cyclization of a vinylic ether intermediate.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cyclization
  • Ethers / chemistry*
  • Lactones / chemical synthesis*
  • Lactones / chemistry
  • Molecular Structure
  • Stereoisomerism
  • Vinyl Compounds / chemistry

Substances

  • Ethers
  • Lactones
  • Vinyl Compounds
  • monocerin