Abstract
Benzylic zinc reagents prepared by direct insertion of zinc to benzylic chlorides in the presence of LiCl undergo smooth cross-coupling reactions with aromatic chlorides, bromides and tosylates using Ni(acac)(2) and PPh(3) as a catalyst system.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzyl Compounds / chemistry*
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Bromides / chemistry*
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Catalysis
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Chlorides / chemistry*
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Nickel / chemistry*
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Tosyl Compounds / chemistry*
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Zinc / chemistry*
Substances
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Benzyl Compounds
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Bromides
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Chlorides
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Tosyl Compounds
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Nickel
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Zinc