Insights into the mode of action of a putative zinc transporter CzrB in Thermus thermophilus

Structure. 2008 Sep 10;16(9):1378-88. doi: 10.1016/j.str.2008.05.014.

Abstract

The crystal structures of the cytoplasmic domain of the putative zinc transporter CzrB in the apo and zinc-bound forms reported herein are consistent with the protein functioning in vivo as a homodimer. NMR, X-ray scattering, and size-exclusion chromatography provide support for dimer formation. Full-length variants of CzrB in the apo and zinc-loaded states were generated by homology modeling with the Zn2+/H+ antiporter YiiP. The model suggests a way in which zinc binding to the cytoplasmic fragment creates a docking site to which a metallochaperone can bind for delivery and transport of its zinc cargo. Because the cytoplasmic domain may exist in the cell as an independent, soluble protein, a proposal is advanced that it functions as a metallochaperone and that it regulates the zinc-transporting activity of the full-length protein. The latter requires that zinc binding becomes uncoupled from the creation of a metallochaperone-docking site on CzrB.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Amino Acid Sequence
  • Bacterial Proteins / chemistry
  • Bacterial Proteins / metabolism*
  • Bacterial Proteins / physiology*
  • Binding Sites
  • Carrier Proteins / metabolism
  • Carrier Proteins / physiology
  • Crystallography, X-Ray
  • Membrane Proteins / chemistry
  • Membrane Proteins / metabolism*
  • Membrane Proteins / physiology*
  • Membrane Transport Proteins / metabolism
  • Membrane Transport Proteins / physiology
  • Models, Biological
  • Models, Molecular
  • Molecular Sequence Data
  • Protein Structure, Secondary
  • Sequence Homology, Amino Acid
  • Substrate Specificity
  • Thermus thermophilus / chemistry
  • Thermus thermophilus / metabolism*
  • Zinc / metabolism*

Substances

  • Bacterial Proteins
  • Carrier Proteins
  • CzrB protein, bacteria
  • Membrane Proteins
  • Membrane Transport Proteins
  • zinc-binding protein
  • Zinc