Na3PbII[B(O3POH)4]: an alkali-metal lead borophosphate with heterocubane-like units Na3PbO4

Stefan Hoffmann; Harold B Tanh Jeazet; Prashanth W Menezes; Yurii Prots; Rüdiger Kniep

doi:10.1021/ic801334g

Na3PbII[B(O3POH)4]: an alkali-metal lead borophosphate with heterocubane-like units Na3PbO4

Inorg Chem. 2008 Nov 17;47(22):10193-5. doi: 10.1021/ic801334g. Epub 2008 Oct 24.

Authors

Stefan Hoffmann¹, Harold B Tanh Jeazet, Prashanth W Menezes, Yurii Prots, Rüdiger Kniep

Affiliation

¹ Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Strasse 40, 01187 Dresden, Germany.

PMID: 18947180
DOI: 10.1021/ic801334g

Abstract

Na 3Pb (II)[B(O 3POH) 4] was synthesized under hydrothermal conditions. The crystal structure determination from single-crystal X-ray diffraction data ( I4 1/ a, Z = 4, a = 6.9182(8) A, c = 27.309 (3) A, V = 1307.0(3) A (3)) revealed the presence of [B(O 3POH) 4] (5-) oligomers and heterocubane-like units Na 3PbO 4 with mixed-occupied metal cation sites.