A strategy for synthesis of ionic metal-organic frameworks

Lijun Han; Suojiang Zhang; Yibo Wang; Xingjuan Yan; Xingmei Lu

doi:10.1021/ic800632r

A strategy for synthesis of ionic metal-organic frameworks

Inorg Chem. 2009 Feb 2;48(3):786-8. doi: 10.1021/ic800632r.

Authors

Lijun Han¹, Suojiang Zhang, Yibo Wang, Xingjuan Yan, Xingmei Lu

Affiliation

¹ Research Laboratory of Green Chemical Engineering and Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, PR China.

PMID: 19117393
DOI: 10.1021/ic800632r

Abstract

For the first time, we designed and synthesized a new kind of ionic metal-organic framework with lanthanide ions and a carboxyl-functionalized ionic liquid, including [Er(4)(mu(3)-OH)(4)(mu(2)-O)(0.5)OL(4)(H(2)O)(3)] x Br(2.90) x Cl(1.10) x 2 H(2)O (MOF-1) and [PrL(H(2)O)(4)Cl] x Br x H(2)O(MOF-2).