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. 2010 Feb;22(2):212-6.
doi: 10.1002/chir.20729.

Stereoselective asymmetric synthesis of (+)-sedamine and (+)-allosedamine

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Stereoselective asymmetric synthesis of (+)-sedamine and (+)-allosedamine

Stéphane Lebrun et al. Chirality. 2010 Feb.

Abstract

A convenient method for the generation of (+)-sedamine and (+)-allosedamine in high optical purity has been elaborated. The key steps are the highly stereoselective 1,2-nucleophilic addition to SAMP hydrazones allowing the installation of the stereogenic center at C2 and ring closing metathesis.

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