Abstract
Exposure of aromatic carboxamides 1e-1m, heteroaromatic carboxamides 1n-1p, and alpha,beta-unsaturated carboxamides 1q-1s to 1,1-dimethylallene in the presence of the a cationic iridium complex derived from [Ir(cod)(2)]BAr(F)(4) and rac-BINAP results in direct C-H prenylation to furnish adducts 2e-2m, 2n-2p, and 2q-2s, respectively, in good isolated yields as single isomers.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Alkadienes / chemistry*
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Catalysis
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Hydrocarbons, Aromatic / chemistry
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Hydrogenation
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Iridium / chemistry*
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Molecular Structure
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Oxidants / chemistry*
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Oxidation-Reduction
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Prenylation*
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Stereoisomerism
Substances
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Alkadienes
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Hydrocarbons, Aromatic
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Oxidants
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Iridium
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propadiene