Electrochemical assessment of the interaction of dihydrogen phosphate with a novel ferrocenyl receptor

J Phys Chem B. 2009 Nov 19;113(46):15141-4. doi: 10.1021/jp9078376.

Abstract

A novel ferrocene-based amide has been synthesized by condensation reaction and characterized by (1)H NMR and UV-vis spectroscopies. The electrochemical properties and anion recognition properties of the ferrocene-based amide were investigated by the CV and UV-vis techniques. An interesting phenomenon was revealed by CV: a second oxidative peak, and the first oxidative peak decreased. Therefore, an effective dihydrogen phosphate recognition sensor is expected from this compound in the future.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anions / chemistry
  • Electrochemical Techniques / methods*
  • Ferrous Compounds / chemical synthesis*
  • Ferrous Compounds / chemistry*
  • Hydrogen / chemistry*
  • Magnetic Resonance Spectroscopy
  • Metallocenes
  • Molecular Conformation
  • Phosphates / chemistry*
  • Spectrophotometry, Ultraviolet

Substances

  • Anions
  • BAE-2Fc
  • Ferrous Compounds
  • Metallocenes
  • Phosphates
  • Hydrogen
  • ferrocene