Condensed heterometallic bidimensional mixed valence Cu(I)/Cu(II)/Ni(II) cyanidometallate

Abstract

A 2D heterometallic mixed valence coordination network, [Cu(2)Ni(dien)(mu-CN)(5)](n) (), built up from fused [Ni(CN)(4)](2-) and [Cu(CN)(3)](2-) cyanidometallate anions and [Cu(dien)](2+) entities is reported.