Design, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on gold(I) phosphine thiolate complex functionalized with crown ether and urea binding units

Xiaoming He; Vivian Wing-Wah Yam

doi:10.1021/ic9021068

Design, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on gold(I) phosphine thiolate complex functionalized with crown ether and urea binding units

Inorg Chem. 2010 Mar 1;49(5):2273-9. doi: 10.1021/ic9021068.

Authors

Xiaoming He¹, Vivian Wing-Wah Yam

Affiliation

¹ Centre for Carbon-Rich Molecular and Nano-Scale Metal-Based Materials Research, Department of Chemistry, and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, PR China.

PMID: 20099846
DOI: 10.1021/ic9021068

Abstract

A ditopic receptor based on gold(I) phosphine thiolate complex [(B15C5Ph(2)P)Au(SC(6)H(4)NHCONHC(6)H(5))] (1) together with a related crown-free analogue, [(Ph(3)P)Au(SC(6)H(4)NHCONHC(6)H(5))] (2), have been designed and synthesized and their photophysical properties studied. Complex 1 featured both a benzo-15-crown-5 cation-binding unit in the auxiliary phosphine ligand and a urea-functionalized thiolate as an anion receptor moiety. The anion- and cation-binding study, salt extraction ability, as well as the cooperativity have been studied using (1)H NMR and ESI-MS techniques.