Abstract
Trinuclear, supramolecular wheel structures are formed spontaneously from the metallation of a Schiff-base-pyrrole macrocycle by Ce(3+) cations, while the related actinide U(3+) cation is instead oxidised to U(4+) and encapsulated by the macrocyclic framework.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cerium / chemistry*
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Crystallography, X-Ray
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Ligands*
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Molecular Conformation
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Pyrroles / chemistry*
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Schiff Bases / chemistry*
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Uranium / chemistry*
Substances
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Ligands
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Pyrroles
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Schiff Bases
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Cerium
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Uranium