Micropatterning of light-sensitive liquid-crystal elastomers

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Nov;80(5 Pt 1):050701. doi: 10.1103/PhysRevE.80.050701. Epub 2009 Nov 24.

Abstract

We demonstrate that photoisomerizable liquid-crystal elastomer soft films can be used as tunable holographic gratings. Optomechanical mechanism of imprinting one-dimensional grating structure into the soft matrix by two-beam uv laser interference can be clearly resolved from the time dependence of the reading beam diffraction patterns. We analyze the observed response in terms of cis-trans isomerization-controlled modulation of the grating profile. The grating period can be tuned reversibly by stretching or contraction of the specimen, either thermomechanically or by applying external stress. Temperature-induced modifications of the grating parameters in the vicinity of the nematic-paranematic phase transition are also examined.

MeSH terms

  • Elastomers / chemistry*
  • Elastomers / radiation effects*
  • Equipment Design
  • Light
  • Liquid Crystals / chemistry*
  • Liquid Crystals / radiation effects*
  • Refractometry / instrumentation*
  • Refractometry / methods
  • Surface Properties

Substances

  • Elastomers