Abstract
A noncovalent macrocycle-within-noncovalent macrocycle assembly is formed from twelve molecules of (+/-)-1 and twelve molecules of MeOH in the solid state. The H-bonded (MeOH)(12) cyclododecamer assumes a crown-shaped geometry that has not previously been predicted theoretically or found experimentally.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Cyclization
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Dimerization
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Hydrogen Bonding
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Macrocyclic Compounds / chemical synthesis
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Macrocyclic Compounds / chemistry*
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Methanol / analogs & derivatives
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Methanol / chemistry*
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Models, Molecular
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Molecular Conformation
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Nanotubes / chemistry*
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Stereoisomerism
Substances
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Macrocyclic Compounds
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Methanol