Biochemical characterization of L-carnitine dehydrogenases from Rhizobium sp. and Xanthomonas translucens

Biosci Biotechnol Biochem. 2010;74(6):1237-42. doi: 10.1271/bbb.100072. Epub 2010 Jun 7.

Abstract

Recently, we obtained two L-carnitine dehydrogenases (CDHs) from soil isolates, Rhizobium sp. (Rs-CDH) and Xanthomonas translucens (Xt-CDH). The respective molecular masses of Rs-CDH and Xt-CDH were approximately 50 kDa and 37 kDa. In this study, the genes encoding both enzymes were cloned. Their primary structures exhibited high identities with those of 3-hydroxyacyl-CoA dehydrogenases. In addition, Rs-CDH had a 180-residue long extra sequence in its C-terminal region. Except for the initial 20 residues, the extra sequence exhibited similarity to thioesterase. The activity of Rs-CDH was affected only slightly by deletion of thioesterase domain, but it was eliminated by the deletion of the whole C-terminal extra sequence. A further deletion experiment indicated that the region of Ala330-Pro335 of Rs-CDH has important functions in catalytic activity. Moreover, based on the deletion experiment on Xt-CDH, the five-residue tail is considered to have a function similar to Ala330-Pro335 of Rs-CDH.

MeSH terms

  • Alcohol Oxidoreductases / chemistry*
  • Alcohol Oxidoreductases / genetics
  • Alcohol Oxidoreductases / metabolism*
  • Amino Acid Sequence
  • Cloning, Molecular
  • Models, Molecular
  • Molecular Sequence Data
  • Protein Conformation
  • Recombinant Fusion Proteins / chemistry
  • Recombinant Fusion Proteins / genetics
  • Recombinant Fusion Proteins / metabolism
  • Rhizobium / enzymology*
  • Rhizobium / genetics
  • Sequence Analysis, DNA
  • Sequence Deletion
  • Xanthomonas / enzymology*
  • Xanthomonas / genetics

Substances

  • Recombinant Fusion Proteins
  • Alcohol Oxidoreductases
  • carnitine dehydrogenase