Abstract
A pyrene-fused subphthalocyanine synthesized from a reaction of 2,7-di-tert-butyl-4,5,9,10-tetracyanopyrene and tetrafluorophthalonitrile exhibits red-shifted Q-band absorption and a unique linear arrangement in the solid state caused by a π-π stacking interaction. The concave conjugation of the SubPc moiety and the planar conjugation of the pyrene moiety enhanced its co-crystallization with C(60) molecules.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Crystallography, X-Ray
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Fullerenes / chemistry
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Indoles / chemical synthesis*
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Indoles / chemistry
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Isoindoles
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Models, Molecular
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Molecular Dynamics Simulation
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Molecular Structure
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Nitriles / chemistry*
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Pyrenes / chemistry*
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Stereoisomerism
Substances
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2,7-di-tert-butyl-4,5,9,10-tetracyanopyrene
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Fullerenes
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Indoles
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Isoindoles
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Nitriles
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Pyrenes
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fullerene C60
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phthalocyanine