Abstract
Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl(3), in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amines / chemistry
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Carbon / chemistry*
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Catalysis
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Chlorides / chemistry*
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Diazonium Compounds / chemistry*
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Ferric Compounds / chemistry*
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Glycine / analogs & derivatives
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Glycine / chemical synthesis*
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Glycine / chemistry
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Molecular Structure
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Nitrogen / chemistry*
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Stereoisomerism
Substances
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Amines
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Chlorides
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Diazonium Compounds
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Ferric Compounds
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Carbon
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Nitrogen
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diazoacetic ester
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Glycine
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ferric chloride