Amperometric sensors based on Ni/Al and Co/Al layered double hydroxides modified electrode and their application for hydrogen peroxide detection

Biosens Bioelectron. 2011 Jan 15;26(5):1970-4. doi: 10.1016/j.bios.2010.08.049. Epub 2010 Aug 20.

Abstract

Two different hydrogen peroxide sensors were constructed with Ni/Al and Co/Al layered double hydroxides (LDHs) modified glassy carbon electrodes (GCE). Ni (Co)/Al-LDHs were synthesized by electrochemical method and were characterized by scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS). The advantages and shortcoming of the two hydrogen peroxide sensors were described in detail. Compared to Co/Al-LDHs modified electrode, sensors fabricated by Ni/Al-LDHs showed quicker heterogeneous electron transfer rate constants (k(s)), lower detection and better reproducibility. But Co/Al-LDHs modified electrode held the advantages of wider linear range and higher sensitivity. Further more, the different catalytic redox mechanisms of hydrogen peroxide on the Ni/Al/GCE and Co/Al/GCE were firstly comparatively explored.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biosensing Techniques / instrumentation*
  • Conductometry / instrumentation*
  • Electrodes*
  • Equipment Design
  • Equipment Failure Analysis
  • Hydrogen Peroxide / analysis*
  • Hydrogen Peroxide / chemistry
  • Hydroxides / chemistry
  • Metals / chemistry*

Substances

  • Hydroxides
  • Metals
  • Hydrogen Peroxide