Gold(III)-catalyzed halogenation of aromatic boronates with N-halosuccinimides

Org Lett. 2010 Dec 3;12(23):5474-7. doi: 10.1021/ol102350v. Epub 2010 Nov 11.

Authors

Di Qiu¹, Fanyang Mo, Zhitong Zheng, Yan Zhang, Jianbo Wang

Affiliation

¹ Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.

PMID: 21070016
DOI: 10.1021/ol102350v

Abstract

Aromatic boronates bearing halogen substituents in the aromatic ring can be synthesized by AuCl(3)-catalyzed halogenations with N-halosuccinimides.