Iron tetrasulfophthalocyanine immobilized on metal organic framework MIL-101: synthesis, characterization and catalytic properties

Olga V Zalomaeva; Konstantin A Kovalenko; Yurii A Chesalov; Maxim S Mel'gunov; Vladimir I Zaikovskii; Vasily V Kaichev; Alexander B Sorokin; Oxana A Kholdeeva; Vladimir P Fedin

doi:10.1039/c0dt01474e

Iron tetrasulfophthalocyanine immobilized on metal organic framework MIL-101: synthesis, characterization and catalytic properties

Dalton Trans. 2011 Feb 21;40(7):1441-4. doi: 10.1039/c0dt01474e. Epub 2011 Jan 10.

Authors

Olga V Zalomaeva¹, Konstantin A Kovalenko, Yurii A Chesalov, Maxim S Mel'gunov, Vladimir I Zaikovskii, Vasily V Kaichev, Alexander B Sorokin, Oxana A Kholdeeva, Vladimir P Fedin

Affiliation

¹ Boreskov Institute of Catalysis, Novosibirsk, Russia.

PMID: 21221448
DOI: 10.1039/c0dt01474e

Abstract

Iron tetrasulfophthalocyanine (FePcS) has been irreversibly inserted into nanocages of the metal organic framework MIL-101 to give a hybrid material FePcS/MIL-101 which demonstrated a superior catalytic performance in the selective oxidation of aromatic substrates with (t)BuOOH than homogeneous FePcS.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alcohols / chemistry
Catalysis
Chromium / chemistry*
Indoles / chemistry*
Ketones / chemical synthesis
Ketones / chemistry
Molecular Structure
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry*
Oxidation-Reduction
Phthalic Acids / chemical synthesis*
Phthalic Acids / chemistry*
tert-Butylhydroperoxide / chemistry

Substances

Alcohols
Indoles
Ketones
Organometallic Compounds
Phthalic Acids
Chromium
iron tetrasulfophthalocyanine
tert-Butylhydroperoxide