Abstract
Indenyl-functionalised BEt(3)-adduct NHCs were prepared by the reaction of imidazolium pro-ligands with LiBEt(3)H. This compound was converted into the indenyl-coordinate molybdenum complex dangling the NHC·BEt(3) moiety as a substituent. The stepwise coordination of NHC afforded a chelate-type mononuclear complex as well as a bimetallic complex.
MeSH terms
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Boranes / chemical synthesis
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Boranes / chemistry*
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Crystallography, X-Ray
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Heterocyclic Compounds / chemical synthesis
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Heterocyclic Compounds / chemistry*
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Imidazoles / chemistry
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Indenes / chemistry*
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Ligands
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Methane / analogs & derivatives*
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Methane / chemistry
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Models, Molecular
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Molecular Structure
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Molybdenum / chemistry*
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
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Stereoisomerism
Substances
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Boranes
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Heterocyclic Compounds
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Imidazoles
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Indenes
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Ligands
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Organometallic Compounds
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carbene
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Molybdenum
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Methane
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triethylborane