The intramolecular migration of a trimethylsilyl group located alpha to a sulfone in substituted cyclohexyl systems

K V Wood; A P Rothwell; M B Anderson; P L Fuchs

doi:10.1002/rcm.1290040102

The intramolecular migration of a trimethylsilyl group located alpha to a sulfone in substituted cyclohexyl systems

Rapid Commun Mass Spectrom. 1990 Jan;4(1):1-4. doi: 10.1002/rcm.1290040102.

Authors

K V Wood¹, A P Rothwell, M B Anderson, P L Fuchs

Affiliation

¹ Department of Chemistry, Purdue University, West Lafayette, Indiana 47907.

PMID: 2134336
DOI: 10.1002/rcm.1290040102

Abstract

The intramolecular migration of a trimethylsilyl moiety alpha to a sulfone group of some modified cyclohexyl ring systems is investigated. The large difference in the relative abundance of this rearrangement ion for similar compounds is related to the stability of the protonated species.

Publication types

Research Support, U.S. Gov't, P.H.S.

MeSH terms

Mass Spectrometry
Sulfones / chemistry*
Trimethylsilyl Compounds / chemistry*

Substances

Sulfones
Trimethylsilyl Compounds

Grants and funding

GM32693/GM/NIGMS NIH HHS/United States