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, 76 (9), 3527-30

Synthesis of Fused Bicyclic Systems With Nitrogen Atom at the Bridgehead, Including Indolizidines and Quinolizidines

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Synthesis of Fused Bicyclic Systems With Nitrogen Atom at the Bridgehead, Including Indolizidines and Quinolizidines

Antonella Pepe et al. J Org Chem.

Abstract

Monocyclic as well as fused bicyclic systems with a nitrogen 10 atom at the bridgehead, including indolizidines and quinolizidines, can be prepared in four steps from N-Boc β-lactams. These easily prepared, highly robust, and flexible building blocks allow the incorporation of chirality and structural diversity, rendering the method feasible for diversity- as well as target-oriented synthesis.

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