Use of perfluorocarboxylic acids to trick cytochrome P450BM3 into initiating the hydroxylation of gaseous alkanes

Angew Chem Int Ed Engl. 2011 May 27;50(23):5315-8. doi: 10.1002/anie.201007975. Epub 2011 Apr 19.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkanes / chemistry*
  • Bacterial Proteins* / chemistry
  • Bacterial Proteins* / metabolism
  • Biocatalysis
  • Carboxylic Acids / chemistry*
  • Cytochrome P-450 Enzyme System* / chemistry
  • Cytochrome P-450 Enzyme System* / metabolism
  • Fluorocarbons / chemistry*
  • Gases / chemistry
  • Hydroxylation
  • Models, Molecular
  • NADPH-Ferrihemoprotein Reductase* / chemistry
  • NADPH-Ferrihemoprotein Reductase* / metabolism
  • Structure-Activity Relationship

Substances

  • Alkanes
  • Bacterial Proteins
  • Carboxylic Acids
  • Fluorocarbons
  • Gases
  • Cytochrome P-450 Enzyme System
  • NADPH-Ferrihemoprotein Reductase
  • flavocytochrome P450 BM3 monoxygenases