Bis(2-amino-1,3-thia-zole-κN)diazido-zinc

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 8;67(Pt 2):m135-6. doi: 10.1107/S1600536810053766.

Abstract

In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra-hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino-thia-zole ligands. Intra-molecular N-H⋯N hydrogen bonds between the amino groups of both 2-amino-thia-zole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Inter-molecular N-H⋯N hydrogen bonds link the mol-ecules into zigzag sheets in the ac plane.