{2,6-Bis[(2,6-diphenyl-phosphan-yl)-oxy]-4-fluoro-phenyl-κP,C,P'}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathia-zin-3-ido-κN)palladium(II)

Benjamin F Wicker; Rachel Seaman; Norris W Hoffman; James H Davis Jr; Richard E Sykora

doi:10.1107/S1600536811002911

{2,6-Bis[(2,6-diphenyl-phosphan-yl)-oxy]-4-fluoro-phenyl-κP,C,P'}(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2,3-oxathia-zin-3-ido-κN)palladium(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 29;67(Pt 2):m286-7. doi: 10.1107/S1600536811002911.

Authors

Benjamin F Wicker¹, Rachel Seaman, Norris W Hoffman, James H Davis Jr, Richard E Sykora

Affiliation

¹ Department of Chemistry, University of South Alabama, Mobile AL 36688-0002, USA.

Abstract

The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L-Pd-L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd-N = 2.127 (2) Å] with a dihedral angle of 76.35 (6)° relative to the square plane. Relatively long phen-yl-acesulfamate C-H⋯O and phen-yl-fluorine C-H⋯F inter-actions consolidate the crystal packing.