2-Azido-3,4;6,7-di-O-isopropyl-idene-α-d-glycero-d-talo-heptopyran-ose

Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 6;66(Pt 3):o525-6. doi: 10.1107/S1600536810003995.

Abstract

In the title compound, C(13)H(21)N(3)O(6), the six-membered ring adopts a twist-boat conformation with the azide group in the bowsprit position. The azide group is disordered over two sets of sites in a 0.642 (10):0.358 (10) ratio. The crystal structure consists of O-H⋯O hydrogen-bonded trimer units. The absolute configuration was determined from the use of d-mannose as the starting material.