Skip to main page content
Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
, 66 (Pt 10), m1260-1

Tri-μ-sulfato-κO:O'-bis-[aqua-(1,10-phenanthroline-κN,N')indium(III)] Dihydrate

Tri-μ-sulfato-κO:O'-bis-[aqua-(1,10-phenanthroline-κN,N')indium(III)] Dihydrate

Fwu Ming Shen et al. Acta Crystallogr Sect E Struct Rep Online.

Abstract

In the title dinuclear In(III) compound, [In(2)(SO(4))(3)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, each In(III) cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water mol-ecule and three sulfate O atoms in a distorted InN(2)O(4) octa-hedral geometry. Three sulfate anions bridge two In(III) cations, forming the dinuclear entities. O-H⋯O and weak C-H⋯O hydrogen bonding is observed in the crystal structure. The crystal structure is further consolidated by π-π stacking between nearly parallel phen ring systems [dihedral angle = 4.2 (4)°], the centroid-centroid distance between benzene rings of adjacent phen ligands being 3.528 (9) Å.

Figures

Fig. 1.
Fig. 1.
View of the title compound with the atom numbering scheme. Displacement ellipsoids for non-H atoms are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
The molecular packing for the title compound. Hydrogen-bonding associations are shown as dotted lines.

Similar articles

See all similar articles

References

    1. Ahmadi, R., Kalateh, K., Abedi, A., Amani, V. & Khavasi, H. R. (2008). Acta Cryst. E64, m1306–m1307. - PMC - PubMed
    1. Bruker (1999). SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bruker (2000). SADABS and SMART Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
    1. Kalateh, K., Ahmadi, R., Ebadi, A., Amani, V. & Khavasi, H. R. (2008). Acta Cryst. E64, m1353–m1354. - PMC - PubMed
Feedback