N'-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)-methyl-idene]adamantane-1-carbo-hydrazide sesquihydrate ethanol hemi-solvate

Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 31;66(Pt 8):o2131. doi: 10.1107/S1600536810029260.

Abstract

In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O·0.5C(2)H(6)O·1.5H(2)O, there are two mol-ecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH-N=CH- chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)° imidazolyl ring at the other end, three mol-ecules of water and one mol-ecule of ethanol. In both independent mol-ecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water mol-ecules; these are linked to other acceptor atoms, generating a layer structure. O-H⋯O and O-H⋯N inter-actions involving the water mol-ecules also occur.